This report introduces a novel method for analysing web datasets based on key dependencies. This particular kind of functional dependencies, widely studied in the field of database theory, allows to evaluate if a set of properties constitutes a key for the set of data considered. When this is the case, there won't be any two instances having identical values for these properties. After giving necessary definitions, we propose an algorithm for detecting minimal keys and pseudo-keys in a RDF dataset. We then use this algorithm to detect keys in datasets published as web data and we apply this approach in two applications: (i) reducing the number of properties to compare in order to discover equivalent instances between two datasets, (ii) detecting errors inside a dataset.