hal-00721928, version 1
Dynamical Ionization Bounds for Atoms
(2012-07-30)
Résumé : We study the long-time behavior of the 3-dimensional repulsive nonlinear Hartree equation with an external attractive Coulomb potential $-Z/|x|$, which is a nonlinear model for the quantum dynamics of an atom. We show that, after a sufficiently long time, the average number of electrons in any finite ball is always smaller than 4Z (respectively 2Z in the radial case). This is a time-dependent generalization of a celebrated result by E.H. Lieb on the maximum negative ionization of atoms in the stationary case. Our proof involves a novel positive commutator argument (based on the cubic weight $|x|^3$) and our findings are reminiscent of the RAGE theorem. In addition, we prove a similar universal bound on the local kinetic energy. In particular, our main result means that, in a weak sense, any solution is attracted to a bounded set in the energy space, whatever the size of the initial datum. Moreover, we extend our main result to Hartree--Fock theory and to the linear many-body Schrödinger equation for atoms.
- 1 :
- Universität Basel
- 2 :
- CNRS : UMR8088 – Université de Cergy Pontoise
- Domaine : Mathématiques/Equations aux dérivées partielles
Physique/Physique mathématique
Mathématiques/Physique mathématique
- hal-00721928, version 1
- http://hal.archives-ouvertes.fr/hal-00721928
- oai:hal.archives-ouvertes.fr:hal-00721928
- Contributeur :
- Soumis le : Mardi 31 Juillet 2012, 09:57:26
- Dernière modification le : Mardi 31 Juillet 2012, 09:57:26


Documents associés
Exporter