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hal-00721928, version 1

Dynamical Ionization Bounds for Atoms

Enno Lenzmann 1, Mathieu LEWIN 2

(2012-07-30)

Résumé : We study the long-time behavior of the 3-dimensional repulsive nonlinear Hartree equation with an external attractive Coulomb potential $-Z/|x|$, which is a nonlinear model for the quantum dynamics of an atom. We show that, after a sufficiently long time, the average number of electrons in any finite ball is always smaller than 4Z (respectively 2Z in the radial case). This is a time-dependent generalization of a celebrated result by E.H. Lieb on the maximum negative ionization of atoms in the stationary case. Our proof involves a novel positive commutator argument (based on the cubic weight $|x|^3$) and our findings are reminiscent of the RAGE theorem. In addition, we prove a similar universal bound on the local kinetic energy. In particular, our main result means that, in a weak sense, any solution is attracted to a bounded set in the energy space, whatever the size of the initial datum. Moreover, we extend our main result to Hartree--Fock theory and to the linear many-body Schrödinger equation for atoms.

  • 1 :  Mathematisches Institut
  • Universität Basel
  • 2 :  Laboratoire d'Analyse, Géométrie et Modélisation (AGM)
  • CNRS : UMR8088 – Université de Cergy Pontoise
  • Domaine : Mathématiques/Equations aux dérivées partielles
    Physique/Physique mathématique
    Mathématiques/Physique mathématique
 
  • hal-00721928, version 1
  • oai:hal.archives-ouvertes.fr:hal-00721928
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  • Soumis le : Mardi 31 Juillet 2012, 09:57:26
  • Dernière modification le : Mardi 31 Juillet 2012, 09:57:26