We introduce a new basis for the algebra of quasisymmetric functions that naturally partitions Schur functions, called quasisymmetric Schur functions. We describe their expansion in terms of fundamental quasisymmetric functions and determine when a quasisymmetric Schur function is equal to a fundamental quasisymmetric function. We conclude by describing a Pieri rule for quasisymmetric Schur functions that naturally generalizes the Pieri rule for Schur functions.