Photoredox/Nickel Dual Catalysis for the C(sp <sup>3</sup> )-C(sp <sup>3</sup> ) Cross-Coupling of Alkylsilicates with Alkyl Halides - Inria - Institut national de recherche en sciences et technologies du numérique Accéder directement au contenu
Article Dans Une Revue European Journal of Organic Chemistry Année : 2017

Photoredox/Nickel Dual Catalysis for the C(sp 3 )-C(sp 3 ) Cross-Coupling of Alkylsilicates with Alkyl Halides

Résumé

Alkylsilicates were engaged under photoredox/nickel dual catalysis conditions with alkyl halides for the first time. The C(sp3)–C(sp3) cross-coupling products were obtained in moderate yields and were accompanied by the homocoupling products of the alkyl halide derivatives. These promising findings are strongly suggestive of the high synthetic potential of the dual catalytic approach for the forging of alkyl carbon–carbon bonds.
Fichier principal
Vignette du fichier
Leveque_2017_Photoredox-Nickel.pdf (1003.95 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-01494010 , version 1 (22-03-2017)

Identifiants

Citer

Christophe Lévêque, Vincent Corcé, Ludwig Chenneberg, Cyril Ollivier, Louis Fensterbank. Photoredox/Nickel Dual Catalysis for the C(sp 3 )-C(sp 3 ) Cross-Coupling of Alkylsilicates with Alkyl Halides. European Journal of Organic Chemistry, 2017, 2017 (15), pp.2118-2121. ⟨10.1002/ejoc.201601571⟩. ⟨hal-01494010⟩
257 Consultations
234 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More