. Anon, Pvc Production Profitability, Deloitte Touche Tohmatsu Limited (DTTL), 2011.

F. Bally, C. A. Serra, V. Hessel, and G. Hadziioannou, Homogeneous polymerization: benefits brought by microprocess technologies to the synthesis and production of polymers, Macromol. React. Eng, vol.4, issue.9, pp.543-561, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00679962

T. Bayer, D. Pysall, and O. Wachsen, Micro mixing effects in continuous radical polymerization, IMRET 3: Proceedings of the Third International Conference on Microreaction Technology, vol.4, pp.165-170, 2000.

M. Benbachir and D. Benjelloun, Investigation of free radical polymerization using diperoxyesters as bifunctional initiators, Polymer, vol.42, issue.18, pp.7727-7738, 2001.

R. S. Benson and J. W. Ponton, Process miniaturization -a route to total environmental acceptability?, Trans. Ind. Chem. Eng, vol.71, issue.A2, pp.160-168, 1993.

N. A. Bichuch, T. G. Ganyukhina, and Y. D. Semchikov, Specific features of suspension copolymerization of vinyl chloride with methyl methacrylate, Russian J. Appl. Chem, vol.76, issue.4, pp.607-609, 2003.

M. D. Bodoc, L. Prat, C. Xuereb, C. Gourdon, and T. Lasuye, Online monitoring of vinyl chloride polymerization in a microreactor using raman spectroscopy, Chem. Eng. Technol, vol.35, issue.4, pp.705-712, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00743489

M. Bowden, P. Donaldson, D. J. Gardiner, J. Birnie, and D. L. Gerrard, Monitoring polyvinyl chloride degradation using raman microline, Anal. Chem, vol.63, issue.24, pp.2915-2918, 1991.

J. Brandrup, E. H. Immergut, E. A. Grulke, A. Abe, and D. R. Bloch, Polymer Handbook, vol.2, 1999.

R. Burgess, Manufacture and Processing of PVC, 2005.

C. Castor, A. Pontier, J. Durand, J. Pinto, and L. Prat, Real time monitoring of the quiescent suspension polymerization of methyl methacrylate in microreactorspart 1. A kinetic study by raman spectroscopy and evolution of droplet size, Chem. Eng. Sci, vol.131, pp.340-352, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01894464

C. Castor, A. Pontier, J. Durand, J. Pinto, and L. Prat, Real time monitoring of the quiescent suspension polymerization of vinyl chloride in microreactors -part 2. a kinetic study by raman spectroscopy and evolution of droplet size, Chem. Eng. Sci, vol.145, pp.279-293, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01927691

J. R. Cerna, G. Morales, G. N. Eyler, and A. I. Canizo, Bulk polymerization of styrene catalyzed by bi-and trifunctional cyclic initiators, J. Appl. Polym. Sci, vol.83, pp.1-11, 2002.

Z. Chang, G. Liu, F. Fang, Y. Tian, and Z. Zhang, gamma-ray-initiated dispersion polymerization of PMA in microreactor, Chem. Eng. J, vol.101, issue.1-3, pp.195-199, 2004.

H. Edwards, K. Johal, and A. Johnson, Ft-raman spectroscopic monitoring of the group-transfer polymerisation of methyl methacrylate, Vibrat. Spectrosc, vol.41, pp.160-169, 2006.

E. J. Emmer and S. G. Bankoff, Suspension copolymerization of vinyl chloride and vinyl acetate, Ind. Eng. Chem, vol.46, issue.4, pp.673-675, 1954.

P. Fernandes, Miniaturization in biocatalysis, Int. J. Mol. Sci, vol.11, issue.3, pp.858-879, 2010.

S. Fityani-trimm, R. Dhib, and A. Penlidis, Free radical polymerization of styrene with a new tetrafunctional peroxide initiator, Macromol. Chem. Phys, vol.204, issue.3, pp.436-442, 2003.

P. J. Flory, Principles of Polymer Chemistry, 1953.

E. Galhardo, C. Franco, and L. Lona, Bifunctional initiators on the polymerization of vinyl acetate, J. Appl. Polym. Sci, vol.127, issue.3, pp.1711-1716, 2013.

R. Gorges, S. Meyer, and G. Kreisel, Photocatalysis in microreactors, J. Photochem. Photobiol., A: Chem, vol.167, issue.2-3, pp.95-99, 2004.

E. Gulari, K. Mckeigue, and K. Y. Ng, Raman and FTIR spectroscopy of polymerization: bulk polymerization of methyl methacrylate and styrene, Macromolecules, vol.17, issue.9, pp.1822-1825, 1984.

T. Iwasaki and J. Yoshida, Free radical polymerization in microreactors, significant improvement in molecular weight distribution control, Macromolecules, vol.38, issue.4, pp.1159-1163, 2005.

K. F. Jensen, Microreaction engineering -is small better?, Chem. Eng. Sci, vol.56, issue.2, pp.293-303, 2001.

P. Joyner and G. Glockler, The raman effect of vinylidene chloride, J. Chem. Phys, vol.20, issue.2, pp.302-306, 1952.

K. Kamio, T. Tadasa, and T. Halwzaki, Process for Preparing Vinyl Chloride/ ethylene Copolymers. PATENT US-3501440 A, 1970.

L. Kang, B. Chung, R. Langer, and A. Khademhosseini, Microfluidics for drug discovery and development: from target selection to product lifecycle management, Drug Disc. Today, vol.1, pp.1-13, 2008.

L. Kiwi-minsker and A. Renken, Microstructured reactors for catalytic reactions, Catal. Today, vol.110, pp.2-14, 2005.

J. L. Koenig, Spectroscopy of Polymers, 1999.

H. Kitamura, S. Koyanagi, and S. Sonegawa, Methods for preparing graft polymers and resin compositions, PATENT US-3717688 A, 1973.

, DaVis StrainMaster Software Manual 7.1. GmbH, Alemanha, 2006.

J. J. Lerou, M. P. Harold, J. Ryley, J. A. O'brien, M. Johnson et al., Microfabricated minichemical systems: technical feasibility, Microsystem Technology for Chemical and Biological Microreactors, vol.132, pp.51-69, 1996.

L. Leroyer, L. Prat, M. Cabassud, C. Gourdon, O. Dechy-cabaret et al., Transposition of a triphosgene-based process for pharmaceutical development: from mg h À1 to kg h À1 of an unsymmetrical urea, Green Process. Synth, vol.2, issue.3, pp.239-250, 2013.

S. A. Liebman, C. R. Foltz, J. F. Reuwer, and R. J. Obremski, Laser raman studies of poly(vinyl chloride), Macromolecules, vol.4, issue.1, pp.134-138, 1971.

F. Lipiecki, S. Maroldo, D. Shenai-khatkhate, and R. Ware, Purification Process Using Microchannel Devices, p.827, 2008.

F. Lipiecki, S. Maroldo, D. V. Shenai-khatkhate, and R. A. Ware, Method of Preparing Organometallic Compounds Using Microchannel Devices, 2009.

V. Macho, M. Kralik, M. Micka, L. Komora, and D. Bakos, Simultaneous statistical suspension copolymerization of vinyl chloride with butyl acrylate and grafting on poly(butyl acrylate), J. Appl. Polym. Sci, vol.68, issue.4, pp.649-656, 1998.

W. Maddans, Some applications of raman spectroscopy in structural studies on poly(vinyl chloride), J. Macromol. Sci, vol.14, issue.1, pp.87-100, 1977.

M. Mahadevan, S. Lee, D. , S. V. , M. Hajri et al., Heterogeneous catalytic polymerization of ethylene in microtubular reactor systems, Chem. Eng. Technol, vol.39, issue.2, pp.293-300, 2016.

N. M. Martyak, Process for the Polymerization of Vinyl Chloride, 2010.

C. S. Marvel, G. D. Jones, T. W. Mastin, and G. L. Schertz, The structure of copolymers of vinyl chloride and vinyl acetate, J. Am. Chem. Soc, vol.64, issue.10, pp.2356-2362, 1942.

M. Massignani, H. Lomas, and G. Battaglia, Polymersomes: A Synthetic Biological Approach to Encapsulation and Delivery, vol.229, pp.115-154, 2010.

R. L. Mccreery, Raman Spectroscopy for Chemical Analysis, vol.157, 2000.

I. C. Mcneill and T. Straiton, Copolymerization of methylmethacrylate with 36cl-vinylchloride, Eur. Polym. J, vol.13, issue.1, pp.17-18, 1977.

S. Müllner and W. Albert, Process for Preparing Vinyl Chloride Polymers, 1967.

I. Nass and I. Leonard, Encyclopedia of PVC, Resin Manufacture and Properties, vol.1, 1998.

C. A. Nielsen, R. W. Chrisman, and R. E. Lapointe, Novel tubing microreactor for monitoring chemical reactions, Anal. Chem, vol.74, issue.13, pp.3112-3117, 2002.

A. Pattekar and M. Kothare, A microreactor for hydrogen production in micro fuel cell applications, J. Microelectromech. Syst, vol.13, issue.1, pp.7-18, 2004.

W. P. Port, E. F. Jordan, W. E. Palm, L. P. Witnauer, J. E. Hansen et al., Polymerizable derivatives of long-chain fatty acids, Indust. Eng. Chem, vol.47, issue.3, pp.472-480, 1955.

W. M. Reiter and A. A. Reventas, Method for Suspension Polymerization of Vinyl Chloride. PATENT US-3757001 A, 1973.

R. Richard, B. Dubreuil, S. Thiebaud-roux, and L. Prat, On-line monitoring of the transesterification reaction carried out in microreactors using near infrared spectroscopy, Fuel, vol.104, pp.318-325, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00782855

A. Salic, A. Tusek, and B. Zelic, Application of microreactors in medicine and biomedicine, J. Appl. Biomed, vol.10, pp.137-153, 2012.

M. J. Scorah, R. Dhib, and A. Penlidis, Free-radical polymerization of methyl methacrylate with a tetrafunctional peroxide initiator, J. Polym. Sci.: Part A: Polym. Chem, vol.42, pp.5647-5661, 2004.

W. Sheng, J. Wu, G. Shan, Z. Huang, and Z. Weng, Free-radical bulk polymerization of styrene with a new trifunctional cyclic peroxide initiator, J. Appl. Polym. Sci, vol.94, pp.1035-1042, 2004.

G. Sielfeld, Process for the Production of Polymer and Copolymers of Vinyl Chloride by Suspension Polymerization and Their Use as Viscosity Reducing Agents in Plastisol Processing, 1984.

L. Soljic, T. Penovic, A. Jukic, and Z. Janovic, Kinetic study of free radical copolymerization of dodecyl methacrylate and styrene using diperoxide initiator, AIDIC Conf. Ser, vol.9, pp.283-292, 2009.

, Graft Copolymerization of Vinyl Chloride and Epichlorohydrine Polymers, 1971.

, Production of Non-Stick Vinyl Chloride Polymer Compositions, 1975.

W. H. Starnes, V. G. Zaikov, H. T. Chung, B. J. Wojciechowski, H. V. Tran et al., Intramolecular hydrogen transfers in vinyl chloride polymerization: routes to doubly branched structures and internal double bonds, Macromolecules, vol.31, pp.1508-1517, 1998.

J. Sun, J. Ju, L. Ji, L. Zhang, and N. Xu, Synthesis of biodiesel in capillary microreactors, Ind. Eng. Chem. Res, vol.47, issue.5, pp.1398-1403, 2008.

D. J. Walsh and G. L. Cheng, The in situ polymerization of vinylchloride in poly (butyl acrylate), Polymer, vol.23, issue.13, pp.1965-1970, 1982.

R. W. Wegeng, C. J. Call, and M. K. Drost, Chemical system miniaturization, Proceedings of the AIChE Spring National Meeting, pp.1-13, 1996.

G. D. Williams, Graft Copolymerization of Methyl Methacrylate Onto Polyvinyl Chloride, vol.3, p.53, 1970.

H. A. Willis, V. J. Zichy, and P. J. Hendra, The laser-raman and infra-red spectra of poly(methyl methacrylate), Polymer, vol.10, pp.737-746, 1969.

B. Yong-zhong, W. Zhi-xue, H. Zhi-ming, and P. Zu-ren, Synthesis of chemically crosslinked poly(vinyl chloride) by vinyl chloride-divinyls suspension copolymerization, Eur. Polym. J, vol.36, pp.981-986, 2000.

P. K. Yonkers, W. F. Keller, D. Ferry, and S. Altscher, Solution Grade PVCCopolymers Prepared by Suspension Polymerization Exhibiting Enhanced Light Stability and Low Haze, 1971.

J. Yuan, M. Pan, X. Wang, and L. Zhang, Dynamic mechanical rheological and morphological studies of polyacrylate-graft-poly (vinyl chloride) suspension resin, Polym. Eng. Sci, vol.47, issue.7, pp.996-1003, 2007.

X. Zhang, S. Stefanick, and F. J. Villani, Application of microreactor technology in process development, Organic Process Res. Develop, vol.8, pp.455-460, 2004.