M. Szycher, Szycher's Handbook of Polyurethanes, First Edition, 1999.

Y. Lu and R. C. Larock, Soybean oil-based, aqueous cationic polyurethane dispersions: Synthesis and properties, Prog. Org. Coat, vol.69, issue.1, pp.31-37, 2010.

H. Liang, L. Liu, J. Lu, M. Chen, and C. Zhang, Castor oil-based cationic waterborne polyurethane dispersions: Storage stability, thermo-physical properties and antibacterial properties

, Ind. Crops. Prod, vol.117, pp.169-178, 2018.

Y. Lu and R. C. Larock, Synthesis and properties of grafted latices from a soybean oil-based waterborne polyurethane and acrylics, J. Appl. Polym. Sci, vol.119, issue.6, pp.3305-3314, 2011.

K. Liu, Z. Su, S. Miao, G. Ma, and S. Zhang, UV-curable enzymatic antibacterial waterborne polyurethane coating, Biochem. Eng. J, vol.113, pp.107-113, 2016.

X. Lai, Y. Song, and M. Liu, Preparation and application of cationic blocked waterborne polyurethane as paper strength agent, J Polym Res, vol.20, issue.8, pp.1-6, 2013.

J. Li, X. Zhang, J. Gooch, W. Sun, H. Wang et al., Photo-and pH-sensitive azocontaining cationic waterborne polyurethane, Polym. Bull, vol.72, issue.4, pp.881-895, 2015.

H. Xin, Y. Shen, and X. Li, Novel cationic polyurethane-fluorinated acrylic hybrid latexes: Synthesis, characterization and properties, Colloids. Surf. A. Physicochem. Eng. Asp, vol.384, issue.1-3, pp.205-211, 2011.

J. Cheng, X. Tang, J. Zhao, T. Shi, P. Zhao et al., Multifunctional cationic polyurethanes designed for non-viral cancer gene therapy, Acta Biomater, vol.30, pp.155-167, 2016.

E. Hans-wilhelm, P. Hans-georg, A. Reinhard, W. A. Rolf, K. Jens et al., Polyurethanes: Versatile Materials and Sustainable Problem Solvers for Today's Challenges, Angew. Chem. Int. Ed, vol.52, pp.9422-9441, 2003.

A. Saetung, A. Rungvichaniwat, I. Campistron, P. Klinpituksa, A. Laguerre et al., Controlled degradation of natural rubber and modification of the obtained telechelic oligoisoprenes: Preliminary study of their potentiality as polyurethane foam precursors, J. Appl
URL : https://hal.archives-ouvertes.fr/hal-00487061

. Polym and . Sci, , vol.117, pp.1279-1289, 2010.

A. Fainleib, R. V. Pires, E. F. Lucas, and B. G. Soares, Degradation of non-vulcanized natural rubber -Renewable resource for fine chemicals used in polymer synthesis, Polimeros, vol.23, issue.4, pp.441-450, 2013.

A. Ciesielski and R. T. Limited, An Introduction to Rubber Technology, Rapra Technology Limited, 1999.

W. Klinklai, S. Kawahara, T. Mizumo, M. Yoshizawa, J. T. Sakdapipanich et al., Depolymerization and ionic conductivity of enzymatically deproteinized natural rubber having epoxy group, Eur. Polym. J, vol.39, issue.8, pp.1707-1712, 2003.

N. Sukhawipat, N. Saetung, J. Pilard, S. Bistac, and A. Saetung, Synthesis and characterization of novel natural rubber based cationic waterborne polyurethane-Effect of emulsifier and diol class chain extender, J. Appl. Polym. Sci, vol.135, pp.1-12, 2017.

A. Saetung, L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, T. Tulyapitak et al., Synthesis, characteristic, and properties of waterborne polyurethane based on natural rubber, J. Appl. Polym. Sci, vol.2012, issue.4, pp.2741-2752
URL : https://hal.archives-ouvertes.fr/hal-00718309

N. Sukhawipat, N. Saetung, and A. Saetung, Synthesis of Novel Cationic Waterborne Polyurethane from Natural Rubber and its Properties Testing, 2016 6 th International Conference on Key Engineering Materials (ICKEM 2016)

A. Saetung, P. Tsupphayakorn-ake, T. Tulyapituk, N. Saetung, P. Phinyocheep et al., The chain extender content and NCO/OH ratio flexibly tune the properties of natural rubberbased waterborne polyurethanes, J. Appl. Polym. Sci, vol.2015, issue.36, p.42505

H. M. Nor and J. R. Ebdon, Telechelic liquid natural rubber: A review, Prog. Polym. Sci, vol.23, issue.2, pp.143-177, 1998.

H. M. Nor and J. R. Ebdon, Ozonolysis of natural rubber in chloroform solution. Part 1. A study by GPC and FTIR spectroscopy, Polymer, issue.7, pp.2359-2365, 2000.

S. K. Gupta, M. R. Kurup, E. Devadoss, R. Muthiah, and S. Thomas, Development and evaluation of a novel binder based on natural rubber and high-energy polyurethane/composite propellants, J. Appl. Polym. Sci, vol.30, issue.3, pp.1095-1112, 1985.

T. Ravindran, M. R. Nayar, and D. J. Francis, Production of hydroxyl-terminated liquid natural rubber-mechanism of photochemical depolymerization and hydroxylation, J. Appl. Polym

. Sci, , vol.35, pp.1227-1239, 1988.

N. Saetung, I. Campistron, S. Pascual, J. Pilard, and L. Fontaine, One-pot synthesis of natural rubber-based telechelic cis-1,4-polyisoprenes and their use to prepare block copolymers by RAFT polymerization, Macromolecules, vol.44, issue.4, pp.784-794, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00569321

S. Gillier-ritoit, D. Reyx, I. Campistron, A. Laguerre, and R. P. Singh, Telechelic cis-1,4-oligoisoprenes through the selective oxidolysis of epoxidized monomer units and polyisoprenic monomer units in cis-1,4-polyisoprenes, J. Appl. Polym. Sci, issue.1, pp.42-46, 2002.

F. Sadaka, I. Campistron, A. Laguerre, and J. Pilard, Controlled chemical degradation of natural rubber using periodic acid: Application for recycling waste tyre rubber, Polym. Degrad. Stab, vol.2012, issue.5, pp.816-828
URL : https://hal.archives-ouvertes.fr/hal-00718316

W. Phetphaisit, C. Bumee, R. Namahoot, J. Ruamcharoen, J. Ruamcharoen et al., Polyurethane polyester elastomer: Innovative environmental friendly wood adhesive from modified PETs and hydroxyl liquid natural rubber polyols, Int. J. Adhes. Adhes, vol.41, pp.127-131, 2013.

N. Kébir, I. Campistron, A. Laguerre, J. Pilard, C. Bunel et al., Use of hydroxytelechelic cis-1,4-polyisoprene (HTPI) in the synthesis of polyurethanes

, Influence of molecular weight and chemical modification of HTPI on the mechanical and thermal properties of PUs, Polymer, vol.46, issue.18, pp.6869-6877, 2005.

B. Burchardt, 3 -Advances in polyurethane structural adhesives, Advances in Structural Adhesive Bonding, pp.35-65, 2010.

K. C. Frisch, Polyurethane handbook, 1986.

G. Hinrichsen, Polyurethane handbook 2nd ed, 1994.

Y. Nakano, K. Okawa, W. Nishijima, and M. Okada, Ozone decomposition of hazardous chemical substance in organic solvents, Water Res, vol.37, issue.11, pp.2595-2598, 2003.

K. Noble and . Waterborne-polyurethanes, Prog. Org. Coat, vol.32, issue.1-4, pp.131-136, 1997.

M. C. Delpech and F. M. Coutinho, Waterborne anionic polyurethanes and poly(urethaneurea)s: influence of the chain extender on mechanical and adhesive properties, Polym. Test, vol.19, issue.8, pp.939-952, 2000.

L. Lei, L. Zhong, X. Lin, Y. Li, and Z. Xia, Synthesis and characterization of waterborne polyurethane dispersions with different chain extenders for potential application in waterborne ink

, Chem. Eng. J, vol.253, pp.518-525, 2014.

J. Li, W. Zheng, W. Zeng, D. Zhang, and X. Peng, Structure, properties and application of a novel low-glossed waterborne polyurethane, Appl. Surf. Sci, vol.307, pp.255-262, 2014.

P. Li, Y. Shen, X. Yang, and G. Li, Preparation and properties of waterborne cationic fluorinated polyurethane, J Polym Res, vol.19, issue.1, p.9786, 2011.

H. Lijie, D. Yongtao, Z. Zhiliang, S. Zhongsheng, and S. Zhihua, Synergistic effect of anionic and nonionic monomers on the synthesis of high solid content waterborne polyurethane, Colloids. Surf. A. Physicochem. Eng. Asp, vol.467, pp.46-56, 2015.

A. A. El-sayed, F. A. Kantouch, and A. Kantouch, Preparation of cationic polyurethane and its application to acrylic fabrics, J. Appl. Polym. Sci, vol.121, issue.2, pp.777-783, 2011.

L. Alibardi and R. Cossu, Pre-treatment of tannery sludge for sustainable landfilling. Waste Manage. (Oxford), vol.52, pp.202-211, 2016.

S. Dixit, A. Yadav, P. D. Dwivedi, and M. Das, Toxic hazards of leather industry and technologies to combat threat: a review, J. Clean. Prod, vol.87, pp.39-49, 2015.

T. Engels, 8 -Thermoset adhesives: epoxy resins, acrylates and polyurethanes, pp.228-253, 2012.

A. E. O'connor and N. Willenbacher, The effect of molecular weight and temperature on tack properties of model polyisobutylenes, Int. J. Adhes. Adhes, vol.24, issue.4, pp.335-346, 2004.

C. L. Jenkins, H. J. Meredith, and J. J. Wilker, Molecular Weight Effects upon the Adhesive Bonding of a Mussel Mimetic Polymer, ACS Appl. Mater. Interfaces, vol.5, issue.11, pp.5091-5096, 2013.

N. Akram, R. S. Gurney, M. Zuber, M. Ishaq, and J. L. Keddie, Influence of Polyol Molecular Weight and Type on the Tack and Peel Properties of Waterborne Polyurethane Pressure-Sensitive Adhesives, Macromol. React. Eng, vol.7, issue.10, pp.493-503, 2013.

V. Mona, B. S. Ebrahimi-;-mehdi, and M. Mohammadseyed, Synthesis and Properties of Ionic Polyurethane Dispersions: Influence of Polyol Molecular Weight. Iran, Polym. J, vol.15, issue.4, pp.323-330, 2006.

M. V. Ebrahimi, M. Barikani, and S. M. Mohaghegh, Synthesis and Properties of Ionic Polyurethane Dispersions: Influence of Polyol Molecular Weight, Iran Polym J, vol.15, issue.4, pp.323-330, 2006.

G. A. Alvarez, M. Fuensanta, V. H. Orozco, L. F. Giraldo, and J. M. Martín-martínez, Hybrid waterborne polyurethane/acrylate dispersion synthesized with bisphenol A-glicidylmethacrylate (Bis-GMA) grafting agent, Prog. Org. Coat, vol.118, pp.30-39, 2018.

Q. Yong, H. Pang, B. Liao, W. Mo, F. Huang et al., Preparation and characterization of low gloss aqueous coating via forming self-roughed surface based on waterborne polyurethane acrylate hybrid emulsion, Prog. Org. Coat, vol.115, pp.18-26, 2018.

H. Fu, C. Yan, W. Zhou, and H. Huang, Nano-SiO2/fluorinated waterborne polyurethane nanocomposite adhesive for laminated films, J. Ind. Eng. Chem, vol.20, issue.4, pp.1623-1632, 2014.

H. Hu, Y. Yuan, and W. Shi, Preparation of waterborne hyperbranched polyurethane acrylate/LDH nanocomposite, Prog. Org. Coat, vol.2012, issue.4, pp.474-479

D. F. Saldanha, C. Canto, L. F. Da-silva, R. J. Carbas, F. J. Chaves et al.,

, Int. J. Adhes. Adhes, vol.47, pp.91-98, 2013.

G. Lim, K. Bodjona, K. P. Raju, S. Fielding, V. Romanov et al., Evolution of mechanical properties of flexible epoxy adhesives under cyclic loading and its effects on composite hybrid bolted/bonded joint design, Compos. Struct, vol.189, pp.54-60, 2018.

Z. Jia, D. Hui, G. Yuan, J. Lair, K. Lau et al., Mechanical properties of an epoxybased adhesive under high strain rate loadings at low temperature environment, Compos. B. Eng, vol.105, pp.132-137, 2016.

M. Ekrem and A. Avc?, Effects of polyvinyl alcohol nanofiber mats on the adhesion strength and fracture toughness of epoxy adhesive joints, Compos. B. Eng, vol.138, pp.256-264, 2018.

A. D. Roberts, Natural rubber science and technology, 1988.

A. Saetung, Preparation of Polyurethane Foams from Hydroxytelechelic Oligoisoprenes Obtained by Controlled Degradation of Natural Rubber: Study of Their Physico-mechanical, Thermal, and Acoustic Properties, 2009.

R. Sethuraj and N. T. Mathew, Natural Rubber: Biology, Cultivation and Technology, 1992.

, Lembaga getchah malaysia, Malaysia rubber board: 2/03/2015, Natural rubber statistics, 2014.

C. A. Uraneck, H. L. Hsieh, and O. G. Buck, Telechelic polymers, Journal of Polymer Science, vol.46, issue.148, pp.535-539, 1960.

N. Kébir, I. Campistron, A. Laguerre, J. F. Pilard, C. Bunel et al., Use of telechelic cis-1 ,4 -polyisoprene cationomers in the synthesis of antibacterial ionic polyurethanes and copolyurethanes bearing ammonium groups, Biomaterials, vol.28, issue.29, pp.4200-4208, 2007.

P. Phinyocheep, C. W. Phetphaisit, D. Derouet, I. Campistron, and J. C. Brosse, Chemical degradation of epoxidized natural rubber using periodic acid: Preparation of epoxidized liquid natural rubber, J. Appl. Polym. Sci, vol.95, issue.1, pp.6-15, 2005.

S. S. Solanky, I. Campistron, A. Laguerre, and J. Pilard, Metathetic selective degradation of polyisoprene: low-molecular-weight telechelic oligomer obtained from both synthetic and natural rubber, Macromol. Chem. Phys, issue.10, pp.1057-1063, 2005.

S. Gutiérrez and M. Tlenkopatchev, Metathesis of renewable products: degradation of natural rubber via cross-metathesis with -pinene using Ru-alkylidene catalysts, Polym. Bull, vol.66, issue.8, pp.1029-1038, 2011.

N. Kébir, G. Morandi, I. Campistron, A. Laguerre, and J. F. Pilard, Synthesis of well defined amino telechelic cis-1,4-oligoisoprenes from carbonyl telechelic oligomers; First studies of their potentialities as polyurethane or polyurea materials precursors, Polymer, vol.46, issue.18, pp.6844-6854, 2005.

R. Tanaka, S. Hirose, and H. Hatakeyama, Preparation and characterization of polyurethane foams using a palm oil-based polyol, Bioresour. Technol, vol.99, issue.9, pp.3810-3816, 2008.

G. Lligadas, J. C. Ronda, M. Galià, and V. Cádiz, Renewable polymeric materials from vegetable oils: A perspective, vol.16, pp.337-343, 2013.

P. Romanowski and . Polyurethane,

M. Alam, D. Akram, E. Sharmin, F. Zafar, and S. Ahmad, Vegetable oil based eco-friendly coating materials: A review article, Arab. J. Chem, vol.7, issue.4, pp.469-479, 2014.

N. Saetung, Synthetic-and natural rubber-based telechelic polyisoprenes: preparation and use for block copolymers via RAFT polymerization. Degree of Doctor of Philosophy, 2010.

M. Ionescu, Chemistry and Technology of Polyols for Polyurethanes, Rapra Technology: United Kingdom, pp.13-17, 2005.

L. R. Zimmerman and . Catalysts, The polyurethanes book, pp.141-146, 2002.

J. Lu, X. Li, Z. Ou, and Q. Chen, Synthesis and properties of cationic waterborne polyurethane emulsion, Gaofenzi Cailiao Kexue Yu Gongcheng, vol.28, issue.3, pp.1-4, 2012.

M. Li, X. Qiang, H. Zhang, Z. Liu, and Z. Yan, Synthesis and characterization of cationic waterborne polyurethane with high solid content, Gaofenzi Cailiao Kexue Yu Gongcheng, vol.30, issue.8, pp.37-42, 2014.

S. Ebnesajjad, Chapter 1 -Introduction and Adhesion Theories A2 -by, Adhesives Technology Handbook, pp.4-17, 2009.

N. M. Zain, S. H. Ahmad, and E. S. Ali, Effect of surface treatments on the durability of green polyurethane adhesive bonded aluminium alloy, Int. J. Adhes. Adhes, vol.55, pp.43-55, 2014.

W. Yu, S. Liu, X. Liu, M. Liu, and W. Shi, Interface reaction in ultrasonic vibration-assisted brazing of aluminum to graphite using Sn-Ag-Ti solder foil, J. Mater. Process

. Technol, , vol.221, pp.285-290, 2015.

R. Matsuzaki, N. Tsukamoto, and J. Taniguchi, Mechanical interlocking by imprinting of undercut micropatterns for improving adhesive strength of polypropylene, Int. J. Adhes. Adhes, vol.68, pp.124-132, 2016.

S. Haldar, T. Sain, and S. Ghosh, A novel high symmetry interlocking micro-architecture design for polymer composites with improved mechanical properties, Int. J. Solids. Struct, vol.124, pp.161-175, 2017.

R. Wang, Y. Shi, T. Li, Y. Pan, Y. Cui et al., Adhesive interfacial characteristics and the related bonding performance of four self-etching adhesives with different functional monomers applied to dentin, J. Dent, vol.62, pp.72-80, 2017.

P. Steiner, Adhesive Failure & Epoxy Failure

Y. Li and S. Ren, Adhesives, Building Decorative Materials, 2011.
URL : https://hal.archives-ouvertes.fr/hal-01597090

, Peel & Adhesion Testing

, Adhesion

L. R. Carolyn, Medical Adhesives in the NICU, Newborn & Infant Nursing Reviews, vol.14, pp.160-165, 2014.

, Epoxy adhesive introduced for food applications. Filtration + Separation, vol.49, p.19, 2012.

J. R. Weitzenböck, 1 -Introduction to using adhesives in marine and offshore engineering

J. R. Weitzenböck and . Ed, Adhesives in Marine Engineering, pp.1-16, 2012.

, Surface Preparation Guide, vol.17

C. Wang, X. Li, B. Du, P. Li, X. Lai et al., Preparation and properties of a novel waterborne fluorinated polyurethane-acrylate hybrid emulsion, Colloid. Polym. Sci, vol.2014, issue.3, pp.579-587

R. Marsalek, Particle Size and Zeta Potential of ZnO, APCBEE Procedia, vol.9, pp.13-17, 2014.

A. Saetung, L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, T. Tulyapitak et al., Synthesis, characteristic, and properties of waterborne polyurethane based on natural rubber, J. Appl. Polym. Sci, vol.2012, issue.4, pp.2742-2752
URL : https://hal.archives-ouvertes.fr/hal-00718309

K. V. Baratha, A. Nourry, and J. Pilard, Synthesis of NR based Polyurethanes containing phosphorylated polymers as chain extenders, Eur. Polym. J, vol.70, pp.317-330, 2015.
URL : https://hal.archives-ouvertes.fr/hal-02117897

A. Saetung, A. Rungvichaniwat, I. Campistron, P. Klinpituksa, A. Laguerre et al., Preparation and physico-mechanical, thermal and acoustic properties of flexible polyurethane foams based on hydroxytelechelic natural rubber, J. Appl. Polym. Sci, vol.2010, issue.2, pp.828-837

C. Tsou, H. Lee, H. Tsai, H. Cheng, and M. Suen, Synthesis and properties of biodegradable polycaprolactone/polyurethanes by using 2 ,6 -pyridinedimethanol as a chain extender, Polym. Degrad. Stab, vol.98, issue.2, pp.643-650, 2013.

I. Kaya and A. Avc?, Synthesis, characterization, and thermal stability of novel poly(azomethine-urethane)s and polyphenol derivatives derived from 2,4-dihydroxy benzaldehyde and toluene-2,4-diisocyanate, Mater. Chem. Phys, vol.2012, issue.1, pp.269-277

N. Zhang, X. Zhou, H. Quan, and A. Sekiya, Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride, J. Fluorine Chem, vol.178, pp.208-213, 2015.

A. Santamaria-echart, I. Fernandes, A. Saralegi, M. R. Costa, F. Barreiro et al., Synthesis of waterborne polyurethane-urea dispersions with chain extension step in homogeneous and heterogeneous media, J. Colloid Interface Sci, vol.476, pp.184-192, 2016.

E. G. Mahoney, W. Sheng, M. Cheng, K. X. Lee, Y. Yan et al., Analyzing the electrooxidation of ethylene glycol and glucose over platinum-modified gold electrocatalysts in alkaline electrolyte using in-situ infrared spectroscopy, J. Power Sources, vol.305, pp.89-96, 2016.

H. Liu, C. Li, and X. S. Sun, Soy-oil-based waterborne polyurethane improved wet strength of soy protein adhesives on wood, Int. J. Adhes. Adhes, vol.73, pp.66-74, 2017.

Y. Jhon, I. Cheong, and J. Kim, Chain extension study of aqueous polyurethane dispersions, Colloids. Surf. A. Physicochem. Eng. Asp, vol.179, issue.1, pp.71-78, 2001.

S. S. Kuhire, C. V. Avadhani, and P. P. Wadgaonkar, New poly(ether urethane)s based on lignin derived aromatic chemicals via A-B monomer approach: Synthesis and characterization

, Polym. J, vol.71, pp.547-557, 2015.

J. Fernández, H. Amestoy, H. Sardon, M. Aguirre, A. L. Varga et al., Effect of molecular weight on the physical properties of poly(ethylene brassylate) homopolymers, J. Mech

, Behav. Biomed. Mater, vol.64, pp.209-219, 2016.

M. Fuensanta and J. M. Martín-martínez, Thermoplastic polyurethane coatings made with mixtures of polyethers of different molecular weights with pressure sensitive adhesion property

, Prog. Org. Coat, vol.118, pp.148-156, 2018.

J. S. Vrentas and C. Chu, Free-volume analysis of solvent self-diffusion in polymer solutions, J. Colloid Interface Sci, vol.130, issue.1, pp.293-295, 1989.

N. Liu, Y. Zhao, M. Kang, J. Wang, X. Wang et al., The effects of the molecular weight and structure of polycarbonatediols on the properties of waterborne polyurethanes, Prog. Org. Coat, vol.82, pp.46-56, 2015.

T. K. Tran, G. Colomines, A. Nourry, J. Pilard, R. Deterre et al., Hydroxyl telechelic natural rubber-based polyurethane: Influence of molecular weight on non-isothermal cure kinetics, Thermochim. Acta, vol.620, pp.51-58, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01620644

O. Chaikumpollert, K. Sae-heng, O. Wakisaka, A. Mase, Y. Yamamoto et al., Low temperature degradation and characterization of natural rubber, Polym. Degrad. Stab, vol.96, issue.11, pp.1989-1995, 2011.

L. Nguyen-dang, S. Le-hoang, M. Malin, J. Weisser, T. Walter et al., Synthesis and characterization of castor oil-segmented thermoplastic polyurethane with controlled mechanical properties, Eur. Polym. J, vol.81, pp.129-137, 2016.

M. Fuensanta, J. A. Jofre-reche, F. Rodríguez-llansola, V. Costa, and J. I. Iglesias,

J. M. Martínez, Structural characterization of polyurethane ureas and waterborne polyurethane urea dispersions made with mixtures of polyester polyol and polycarbonate diol, Prog. Org. Coat, vol.112, pp.141-152, 2017.

W. Lin and W. Lee, Effects of the NCO/OH molar ratio and the silica contained on the properties of waterborne polyurethane resins, Colloids. Surf. A. Physicochem. Eng. Asp, vol.522, pp.453-460, 2017.

R. N. Rai, S. Kant, R. S. Reddi, S. Ganesamoorthy, and P. K. Gupta, Solid state synthesis, crystal growth and optical properties of urea and p-chloronitrobenzene solid solution, J. Solid State Chem, vol.233, pp.244-251, 2016.

K. M. Hercule, Z. Yan, and M. M. Christophe, Preparation and Characterization of

, Waterborne Polyurethane Crosslinked by Urea Bridges, 2011.

A. Asefnejad, M. T. Khorasani, A. Behnamghader, B. Farsadzadeh, and S. Bonakdar, Manufacturing of biodegradable polyurethane scaffolds based on polycaprolactone using a phase separation method: physical properties and in vitro assay, International Journal of Nanomedicine, vol.6, pp.2375-2384, 2011.

B. Kordi?, M. Kova?evi?, T. Sloboda, A. Vidovi?, and B. Jovi?, FT-IR and NIR spectroscopic investigation of hydrogen bonding in indole-ether systems, J. Mol. Struct, vol.1144, pp.159-165, 2017.

N. D. Merekalova, G. N. Bondarenko, Y. I. Denisova, L. B. Krentsel, A. D. Litmanovich et al., Effect of chain structure on hydrogen bonding in vinyl acetate -vinyl alcohol copolymers, J. Mol. Struct, vol.1134, pp.475-481, 2017.

J. Joseph and E. D. Jemmis, Red-, Blue-, or No-Shift in Hydrogen Bonds: A Unified Explanation, J. Am. Chem. Soc, vol.129, issue.15, pp.4620-4632, 2007.

Y. Li, B. A. Noordover, R. A. Van-benthem, and C. E. Koning, Bio-based poly(urethane urea) dispersions with low internal stabilizing agent contents and tunable thermal properties, Prog. Org. Coat, vol.86, pp.134-142, 2015.

V. R. Patel and Y. K. Agrawal, Nanosuspension: An approach to enhance solubility of drugs

, J. Adv. Pharm. Technol. Res, vol.2, issue.2, pp.81-87, 2011.

S. Sundar, N. Vijayalakshmi, S. Gupta, R. Rajaram, and G. Radhakrishnan, Aqueous dispersions of polyurethane-polyvinyl pyridine cationomers and their application as binder in base coat for leather finishing, Prog. Org. Coat, vol.56, issue.2, pp.178-184, 2006.

D. E. Packham, Surface energy, surface topography and adhesion, Int. J. Adhes. Adhes, vol.23, issue.6, pp.437-448, 2003.

Y. H. Lin, K. H. Liao, N. K. Chou, S. S. Wang, S. H. Chu et al., UV-curable low-surface-energy fluorinated poly(urethane-acrylate)s for biomedical applications

J. , , vol.44, pp.2927-2937, 2008.

H. Hwang and H. Kim, UV-curable low surface energy fluorinated polycarbonate-based polyurethane dispersion, J. Colloid Interface Sci, vol.362, issue.2, pp.274-284, 2011.

T. Ç. Çanak and I. E. Serhatl?, Synthesis of fluorinated urethane acrylate based UV-curable coatings, Prog. Org. Coat, vol.76, issue.2, pp.388-399, 2013.

G. Zheng, M. Lu, and X. Rui, The effect of polyether functional polydimethylsiloxane on surface and thermal properties of waterborne polyurethane, Appl. Surf. Sci, vol.399, pp.272-281, 2017.

Y. Feng, H. Liang, Z. Yang, T. Yuan, Y. Luo et al., A SolventFree and Scalable Method To Prepare Soybean-Oil-Based Polyols by Thiol-Ene Photo-Click Reaction and Biobased Polyurethanes Therefrom, ACS Sustain. Chem. Eng, vol.2017, issue.8, pp.7365-7373

M. E. Mirghani, H. M. Salleh, Y. B. Man, and I. Jaswir, Rapid authentication of leather and leather products, Adv. Nat. Appl. Sci, vol.2012, issue.5, pp.651-659

L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, A. Saetung, J. F. Pilard et al., Synthesis and characterisation of waterborne polyurethane adhesives from hydroxyl terminated natural rubber, J. Rubber Res, vol.15, issue.4, pp.217-229, 2012.

C. Lim, D. W. Lee, J. N. Israelachvili, Y. Jho, and D. S. Hwang, Contact time-and pHdependent adhesion and cohesion of low molecular weight chitosan coated surfaces

. Polym, , vol.117, pp.887-894, 2015.

C. Thornton, S. J. Cummins, and P. W. Cleary, On elastic-plastic normal contact force models, with and without adhesion, Powder Technol, vol.315, pp.339-346, 2017.

D. Derouet, S. Mulder-houdayer, and J. C. Brosse, Comparative study of the epoxidation of natural and synthetic rubber latices, J. Rubber Res, vol.9, issue.1, pp.1-20, 2006.

D. R. Burfield, K. L. Lim, and K. S. Law, Epoxidation of natural rubber latices: Methods of preparation and properties of modified rubbers, J. Appl. Polym. Sci, vol.29, issue.5, pp.1661-1673, 1984.

A. A. El-sayed, F. A. Kantouch, and A. Kantouch, Preparation of cationic polyurethane and its application to acrylic fabrics, J. Appl. Polym. Sci, vol.121, pp.777-783, 2011.

Y. Lu and R. C. Larock, Soybean oil-based, aqueous cationic polyurethane dispersions: Synthesis and properties, Prog. Org. Coat, vol.69, pp.31-37, 2010.

C. Chang and K. Lu, Natural castor oil based 2-package waterborne polyurethane wood coatings, Prog. Org. Coat, vol.75, pp.435-443, 2012.

C. Fu, Z. Zheng, Z. Yang, Y. Chen, and L. Shen, A fully bio-based waterborne polyurethane dispersion from vegetable oils: From synthesis of precursors by thiol-ene reaction to study of final material, Prog. Org. Coat, vol.77, pp.53-60, 2014.

S. Saalah, L. C. Abdullah, M. M. Aung, M. Z. Salleh, D. R. Biak et al., Waterborne polyurethane dispersions synthesized from jatropha oil, Ind. Crops Prod, vol.64, pp.194-200, 2015.

E. Sharmin, F. Zafar, D. Akram, M. Alam, and S. Ahmad, Recent advances in vegetable oils based environment friendly coatings: A review, Ind. Crops Prod, vol.76, pp.215-229, 2015.

X. Zhou, Y. Li, C. Fang, S. Li, Y. Cheng et al., Recent Advances in Synthesis of Waterborne Polyurethane and Their Application in Water-based Ink: A Review, J. Mater. Sci. Technol, vol.31, pp.708-722, 2015.

A. Saetung, A. Rungvichaniwat, I. Campistron, P. Klinpituksa, A. Laguerre et al., Controlled degradation of natural rubber and modification of the obtained telechelic oligoisoprenes: Preliminary study of their potentiality as polyurethane foam precursors, J. Appl. Polym. Sci, vol.117, pp.1279-1289, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00487061

A. Ciesielski, An Introduction to Rubber Technology, Rapra Technology Limited, 1999.

A. Fainleib, R. V. Pires, E. F. Lucas, and B. G. Soares, Degradation of non-vulcanized natural rubber -Renewable resource for fine chemicals used in polymer synthesis, Polimeros, vol.23, pp.441-450, 2013.

A. Saetung, L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, T. Tulyapitak et al., Synthesis, characteristic, and properties of waterborne polyurethane based on natural rubber, J. Appl. Polym. Sci, vol.124, pp.2742-2752, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00718309

A. Saetung, A. Rungvichaniwat, I. Campistron, P. Klinpituksa, A. Laguerre et al., Preparation and physico-mechanical, thermal and acoustic properties of flexible polyurethane foams based on hydroxytelechelic natural rubber, J. Appl. Polym. Sci, vol.117, pp.828-837, 2010.

A. Saetung, P. Tsupphayakorn-ake, T. Tulyapituk, N. Saetung, P. Phinyocheep et al., The chain extender content and NCO/OH ratio flexibly tune the properties of natural rubberbased waterborne polyurethanes, J. Appl. Polym. Sci, vol.132, p.42505, 2015.

?. Kaya and A. Avc?, Synthesis, characterization, and thermal stability of novel poly(azomethineurethane)s and polyphenol derivatives derived from 2,4-dihydroxy benzaldehyde and toluene-2,4-diisocyanate, Mater. Chem. Phys, vol.133, pp.269-277, 2012.

N. Zhang, X. Zhou, H. Quan, and A. Sekiya, Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride, J. Fluorine Chem, vol.178, pp.208-213, 2015.

K. V. Baratha, A. Nourry, and J. Pilard, Synthesis of NR based Polyurethanes containing phosphorylated polymers as chain extenders, Eur. Polym. J, vol.70, pp.317-330, 2015.
URL : https://hal.archives-ouvertes.fr/hal-02117897

, Anuwat Saetung, vol.4

, UMR CNRS 6283, Institut des Mol ecules et Mat eriaux du Mans (IMMM), 72085.

, E -mail: snitinart@hotmail.com) and A. Saetung (E -mail: anuwat.s@psu.ac.th) ABSTRACT: Novel cationic waterborne polyurethanes (cWPU) were synthesized by step-growth polymerization of hydroxyl telechelic natural rubber, molecular weight of 2800 g mol 21 , toluene-2,4-diisocyanate, N-methyl diethanolamine (NMDEA) as an emulsifier. The chemical structure of cWPU was confirmed by 1 H-nuclear magnetic resonance and Fourier transform infrared spectroscopy. The amounts of NMDEA and ethylene glycol under isocyanate (NCO) index of 100 on the properties of cWPU were studied. It was found that cWPU was stable under the concentration of NMDEA more than 1.50 mol and the particle sizes decreased with increasing of NMDEA content. Also, contact angle shows more hydrophilic materials by increasing of NMDEA. Extended cWPU was found in two ranges of nano size. Chain extender has strongly affected cWPU film formation, increasing of mechanical properties, and thermal properties. In addition, stress-strain curve and scanning electron microscopy image shows the change of behavior from soft elastic to ductile plastic by adding ethylene glycol, J. Appl. Polym. Sci, vol.134, 2017.

M. Szycher, Szycher's Handbook of Polyurethanes, 1999.

Y. Nakano, K. Okawa, W. Nishijima, and M. Okada, Water Res, vol.37, p.2595, 2003.

K. Kawamura, M. Vestergaard, M. Ishiyama, N. Nagatani, T. Hashiba et al., Measurement, p.490, 2006.

, DMTA curves of cWPU film. (a) Tan d, (b) storage modulus

A. Wileyonlinelibrary and . Com/app,

, J. APPL. POLYM. SCI, 2017.

M. Mabrook and P. Hawkins, Sensors, vol.2, p.374, 2002.

Z. Zhu and R. J. Wu, J. Taiwan Inst. Chem. Eng, vol.50, p.276, 2015.

K. Noble, Prog. Org. Coat, vol.32, p.131, 1997.

M. C. Delpech and F. M. Coutinho, Polym. Test, vol.19, p.939, 2000.

A. Saetung, L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, T. Tulyapitak et al., J. Appl. Polym. Sci, vol.124, p.2741, 2012.

L. Lei, L. Zhong, X. Lin, Y. Li, and . Xia, Z. Chem. Eng. J, vol.253, p.518, 2014.

J. Li, W. Zheng, W. Zeng, D. Zhang, and X. Peng, Appl. Surf. Sci, p.255, 2014.

P. Li, Y. Shen, X. Yang, and G. Li, J. Polym. Res, 2011.

Y. Lu and R. C. Larock, Prog. Org. Coat, p.31, 2010.

J. Li, X. Zhang, J. Gooch, W. Sun, H. Wang et al., Polym. Bull, vol.72, p.881, 2015.

H. Lijie, D. Yongtao, Z. Zhiliang, S. Zhongsheng, and S. Zhihua, Colloids Surf. A, p.46, 2015.

N. M. Zain, E. N. Roslin, and S. Ahmad, Int. J. Adhes. Adhes, vol.71, p.1, 2016.

S. Sundar, N. Vijayalakshmi, S. Gupta, R. Rajaram, and G. Radhakrishnan, Prog. Org. Coat, vol.56, p.178, 2006.

A. A. El-sayed, F. A. Kantouch, and A. Kantouch, J. Appl. Polym. Sci, p.33558, 2011.

L. Liu, X. Wu, and T. Li, J. Power Sources, p.397, 2014.

T. Yang, W. Chin, J. Cherng, and M. Shau, Biomacromolecules, 1926.

J. Cheng, X. Tang, J. Zhao, T. Shi, P. Zhao et al., , vol.30, p.155, 2016.

W. C. Hung, M. D. Shau, H. C. Kao, M. F. Shih, and J. Y. Cherng, J. Controlled Release, vol.133, p.68, 2009.

P. Li, Y. Shen, X. Yang, and G. Li, J. Polym. Res, 2001.

H. Xin, Y. Shen, and X. Li, Colloids Surf. A, p.205, 2011.

Y. Lu and R. C. Larock, J. Appl. Polym. Sci, vol.119, p.3305, 2011.

W. Phetphaisit, C. Bumee, R. Namahoot, J. Ruamcharoen, J. Ruamcharoen et al., Int. J. Adhes. Adhes, p.127, 2013.

W. Panwiriyarat, V. Tanrattanakul, J. Pilard, P. Pasetto, and C. Khaokong, J. Polym. Environ, p.807, 2013.

A. Saetung, P. Tsupphayakorn-ake, T. Tulyapituk, N. Saetung, P. Phinyocheep et al., J. Appl. Polym. Sci, vol.132, p.42505, 2015.

A. Thitithammawong, A. Rungvichaniwat, and S. Srangkum, Macromol. Symp, vol.354, p.354, 2015.

A. Saetung, A. Rungvichaniwat, I. Campistron, P. Klinpituksa, A. Laguerre et al., J. Appl. Polym. Sci, p.828, 2010.

H. M. Nor and J. R. Ebdon, Prog. Polym. Sci, vol.23, p.143, 1998.

H. M. Nor, J. R. Ebdon, and . Polymer, , p.2359, 2000.

S. K. Gupta, M. R. Kurup, E. Devadoss, R. Muthiah, and S. Thomas, J. Appl. Polym. Sci, 1095.

T. Ravindran, M. R. Nayar, and D. J. Francis, J. Appl. Polym. Sci, vol.35, p.1227, 1988.

N. Saetung, I. Campistron, S. Pascual, J. Pilard, and L. Fontaine, Macromolecules, p.784, 2011.

A. Saetung, A. Rungvichaniwat, I. Campistron, P. Klinpituksa, A. Laguerre et al., J. Appl. Polym. Sci, p.1279, 2010.

S. Gillier-ritoit, D. Reyx, I. Campistron, A. Laguerre, and R. P. Singh, J. Appl. Polym. Sci, vol.87, p.42, 2002.

F. Sadaka, I. Campistron, A. Laguerre, and J. Pilard, Polym. Degrad. Stab, p.816, 2012.

A. Saetung, L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, T. Tulyapitak et al., J. Appl. Polym. Sci, vol.124, p.2742, 2012.

N. K-ebir, I. Campistron, A. Laguerre, J. Pilard, C. Bunel et al., Polymer, vol.46, p.6869, 2005.

Y. Jhon, I. Cheong, and J. Kim, Colloids Surf. A, p.71, 2001.

C. Wang, X. Li, B. Du, P. Li, X. Lai et al., Colloid. Polym. Sci, vol.292, p.579, 2014.

W. Fan, W. Du, Z. Li, N. Dan, and . Huang, J. Prog. Org. Coat, vol.86, p.125, 2015.

K. V. Baratha, A. Nourry, and J. Pilard, Eur. Polym. J, vol.70, p.317, 2015.

C. Tsou, H. Lee, H. Tsai, H. Cheng, and M. Suen, Polym. Degrad. Stab, vol.98, p.643, 2013.

E. G. Mahoney, W. Sheng, M. Cheng, K. X. Lee, Y. Yan et al., J. Power Sources, p.89, 2016.

_. I. Kaya, A. Avc?, and . Mater, Chem. Phys, p.269, 2012.

N. Zhang, X. Zhou, H. Quan, and A. Sekiya, J. Fluorine Chem, p.208, 2015.

X. Gao, Y. Zhu, S. Zhou, W. Gao, Z. Wang et al., Colloids Surf. A, p.312, 2011.

C. Fu, Z. Zheng, Z. Yang, Y. Chen, and L. Shen, Prog. Org. Coat, vol.77, p.53, 2014.

S. S. Kuhire, C. V. Avadhani, and P. P. Wadgaonkar, Eur. Polym. J, p.547, 2015.