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, All Rights Reserved, pp.1880-1884

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J. G. Lundin, P. N. Coneski, P. A. Fulmer, and J. H. Wynne, Relationship between Surface Concentration of Amphiphilic Quaternary Ammonium Biocides in Electrospun Polymer Fibers and Biocidal Activity, React. Funct. Polym, vol.77, 2014.

, All Rights Reserved, pp.39-46

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S. Pané, E. Gómez, and E. Vallés, Influence of a Magnetic Field during the CoNi Electrodeposition in the Presence of Magnetic Nanoparticles, J. Electroanal. Chem, issue.2, pp.117-123, 2008.

S. Pané, E. Gómez, J. Garcia-amorós, D. Velasco, and E. Vallés, Modulation of the Magnetic Properties of CoNi Coatings by Electrodeposition in the Presence of a Redox Cationic Surfactant, Appl. Surf. Sci, vol.253, issue.5, pp.2964-2968, 2006.

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, ANNEXE Zoom sur les protons aromatiques de 4-éthyl-4'-(2 hydroxyéthoxy)azobenzène

, Liste des publications et des communications

A. Franche, A. Fayeulle, L. Lins, M. Billamboz, I. Pezron et al., Amphiphilic azobenzenes: Antibacterial activities and biophysical investigation of their interaction with bacterial membrane lipids Bioorganic Chemistry, p.103399, 2019.

A. Franche, C. Imbs, A. Fayeulle, F. Merlier, M. Billamboz et al., Zinc-mediated reactions on salicylaldehyde for Botrytis cinerea control, Chinese Chemical Letters, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02362165

A. Franche, A. Fayeulle, I. Pezron, M. Deleu, and E. Léonard, Antibacterial intelligent amphiphiles, ISGC 2019 International Conference, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02192532

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A. Franche, 75% yield. 1 H NMR (400 MHz, 2019.

. Mhz,

(. 2h, D. , and J. =. , 3 Hz); 6.92 (2H, d, J = 8.8 Hz); 2.68 (2H, t

H. Nmr, CDCl 3 ): ? 7.86 (2H, d, J = 8.6 Hz); 7.8 (2H, d, J = 8.1 Hz), vol.7, issue.400

, 7 mmol) filtration under vacuum, the solvent was evaporated. The residue was purified by silica gel chromatography, Cyclohexane/EtOAc, vol.19

, ×2); 69.6; 61.3. 2b (orange solid, 3.58 g, 67% yield) mp = 126°C, 1 H NMR (400 MHz

, FTIR: 3334 cm ?1 (w), 2931 cm ?1 (w), 1597 cm ?1 (s), 1500 cm ?1 (s), 1252 cm ?1 (s), 1079 cm ?1 (s), 1045 cm ?1 (s), pp.841-842

, 2c [37] (orange solid, 1.98 g, 34% yield) 1 H NMR (400 MHz, HRMS (ESI+) m/z calculated for

D. 2h and J. =. ,

, Synthesis of a 3a-3d To a solution of 2a-2d (4 mmol) dichloromethane (25 mL), tri

, Compounds 3a-3d was dissolved in a H 2 O/acetone mixture (2:1)

-. Trans and . 4a,

D. Mhz,

. Trans-et-azotai-4b,

M. Mhz,

D. 2h and J. =. , 1 Hz), vol.7, p.36

. Trans-bu-azotai-4c,

M. Mhz,

D. 2h, J. , D. , and J. =. , , vol.7, p.33

. Trans-hex, AZOTAI 4d orange solid, 495 mg, 25% yield. mp = 196°C 1 H NMR (400 MHz, MeOD) 7.92 (2H, d, J = 8.7 Hz), vol.7

, WHO publishes list of bacteria for which new antibiotics are urgently, vol.23, 2018.

V. Defraine, M. Fauvart, and J. Michiels, Fighting bacterial persistence: current and emerging anti-persister strategies and therapeutics, Drug Resist. Updat, vol.38, pp.12-26, 2018.

N. Drillaud, E. Banaszak-léonard, I. Pezron, and C. Len, Synthesis and evaluation of a photochromic surfactant for organic reactions in aqueous media, J. Org. Chem, vol.77, issue.21, pp.9553-9561, 2012.
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M. Billamboz, F. Mangin, N. Drillaud, C. Chevrin-villette, E. Banaszak-léonard et al., Micellar catalysis using a photochromic surfactant: application to the Pdcatalyzed Tsuji-Trost reaction in water, J. Org. Chem, vol.79, issue.2, pp.493-500, 2014.
URL : https://hal.archives-ouvertes.fr/hal-02194016

T. J. Sorensen, K. Kjaer, D. W. Breiby, and B. W. Laursen, Synthesis of novel amphiphilic azobenzenes and X-ray scattering studies of their langmuir monolayers, Langmuir, vol.24, pp.3223-3227, 2008.

E. Léonard, F. Mangin, C. Villette, M. Billamboz, and C. Len, Azobenzenes and catalysis, Catal. Sci. Technol, vol.6, issue.2, pp.379-398, 2016.

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, All Rights Reserved

N. K. Sharma, M. Singh, and A. Bhattarai, Hydrophobic study of increasing alkyl chain length of platinum surfactant complexes: synthesis, characterization, micellization, thermodynamics, thermogravimetrics and surface morphology, RSC Adv, vol.6, issue.93, pp.90607-90623, 2016.

J. Oremusová, Micellization of alkyl trimethyl ammonium bromides in aqueous solutions-Part 1: Critical micelle concentration (CMC) and ionization degree, Tenside Surfactants Deterg, vol.49, issue.3, pp.231-240, 2012.

A. Petek, M. Krajnc, and A. Petek, The role of intermolecular interactions in the micellization process of alkyltrimethyl ammonium bromides in water

A. Franche, Bioorganic Chemistry, vol.94, p.103399, 2020.

, Surfactants Deterg, vol.53, issue.1, pp.56-63, 2016.

L. Poirel, A. Jayol, and P. Nordmann, Polymyxins: antibacterial activity, susceptibility testing, and resistance mechanisms encoded by plasmids or chromosomes, Clin. Microbiol. Rev, vol.30, issue.2, pp.557-596, 2017.

J. A. Silverman, N. G. Perlmutter, and H. M. Shapiro, Correlation of daptomycin bactericidal activity and membrane depolarization in staphylococcus aureus, Antimicrob. Agents Chemother, vol.47, issue.8, pp.2538-2544, 2003.

L. Guo, M. Long, Y. Huang, G. Wu, W. Deng et al., Antimicrobial and disinfectant resistance of Escherichia coli isolated from giant pandas, J. Appl. Microbiol, vol.119, issue.1, pp.55-64, 2015.

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R. F. Epand, P. B. Savage, and R. M. Epand, Bacterial lipid composition and the antimicrobial efficacy of cationic steroid compounds (ceragenins), Biochim. Biophys. Acta BBA -Biomembr, vol.1768, issue.10, pp.2500-2509, 2007.

H. Heerklotz and J. Seelig, Leakage and lysis of lipid membranes induced by the lipopeptide surfactin, Eur. Biophys. J, vol.36, issue.4-5, pp.305-314, 2007.

M. Deleu, S. Gatard, E. Payen, L. Lins, K. Nott et al., D-Xylose-based bolaamphiphiles: synthesis and influence of the spacer nature on their interfacial and membrane properties, Comptes Rendus Chim, vol.15, issue.1, pp.68-74, 2012.
URL : https://hal.archives-ouvertes.fr/hal-02540470

D. Marsh, Lateral pressure in membranes, Biochim. Biophys. Acta BBA -Rev. Biomembr, vol.1286, issue.3, pp.9-12, 1996.

C. Chen, K. Li, and Y. Chu, Reaction-based detection of chemical warfare agent mimics with affinity ionic liquids, Anal. Chem. Wash. DC U. S, vol.90, p.2019, 2018.

, All Rights Reserved

L. Johnson, B. Ringstrand, and P. Kaszynski, A convenient preparation of long chain 4-(4-n-alkylphenylazo)phenols and their 4-pentylbenzoate esters, Liq. Cryst, vol.36, issue.2, pp.179-185, 2009.

K. Jia, X. Zhang, L. Zhang, L. Yu, Y. Wu et al., Photoinduced reconfiguration of complex emulsions using a photoresponsive surfactant, Langmuir, vol.34, issue.38, pp.11544-11552, 2018.

C. Xiong, M. Xie, and R. Sun, Responsiveness and morphology study of dual stimulicontrolled supramolecular polymer, Macromol. Rapid Commun, vol.38, issue.19, pp.1700358-1700366, 2017.

N. Yoshino, A. Nagasaki, Y. Kondo, and M. Abe, Syntheses of amphiphiles containing two azobenzene units in a molecule, J. Jpn. Oil Chem. Soc, vol.44, issue.12, pp.1075-1085, 1995.

A. Damijonaitis, J. Broichhagen, T. Urushima, K. Hüll, J. Nagpal et al., AzoCholine enables optical control of alpha 7 nicotinic acetylcholine receptors in neural networks, ACS Chem. Neurosci, vol.6, issue.5, pp.701-707, 2015.

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