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Article Dans Une Revue Journal de Physique IV Proceedings Année : 1992

Model of polarization conductivity in ionically conducting glasses

J. Giuntini
  • Fonction : Auteur
F. Buet
  • Fonction : Auteur
F. Henn
  • Fonction : Auteur
J. Zanchetta
  • Fonction : Auteur
J. Vanderschueren
  • Fonction : Auteur

Résumé

We have used a hopping conduction model to calculate the frequency-dependent polarization conductivity, [MATH] in ionically conducting glasses, and we have assumed that a short-range ionic hopping mechanism occurs based on a fluctuation process. We have underlined the fundamental differences between the frequency-dependent polarization conductivity due to "bound-charge" and the dc conductivity related to "free-charge" diffusion. The law [MATH] is observed as for electronic charge-carriers in amorphous substances. The expression of parameter s is modified by the introduction of a term connected with the fluctuation probability. A plot of the function T/1-s = f(T) shows a striking difference in behaviour (slopes) between ionic glasses (Na2O-3SiO2, (Ag2S)x (GeS21-x) and electronic amorphous solids.

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jpa-00251289 , version 1 (04-02-2008)

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J. Giuntini, F. Buet, F. Henn, J. Zanchetta, J. Vanderschueren. Model of polarization conductivity in ionically conducting glasses. Journal de Physique IV Proceedings, 1992, 02 (C2), pp.C2-145-C2-148. ⟨10.1051/jp4:1992218⟩. ⟨jpa-00251289⟩

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