The assimilation of data from Earth observation satellites into numerical models is considered to be the path forward to estimate snow cover distribution in mountain catchments, providing accurate information on the mountainous snow water equivalent (SWE). The land surface temperature (LST) can be observed from space, but its potential to improve SWE simulations remains underexplored. This is likely due to the insufficient temporal or spatial resolution offered by the current thermal infrared (TIR) missions. However, three planned missions will provide global-scale TIR data at much higher spatiotemporal resolution in the coming years. To investigate the value of TIR data to improve SWE estimation, we developed a synthetic data assimilation (DA) experiment at five snow-dominated sites covering a latitudinal gradient in the Northern Hemisphere. We generated synthetic true LST and SWE series by forcing an energy balance snowpack model with the ERA5-Land reanalysis. We used this synthetic true LST to recover the synthetic true SWE from a degraded version of ERA5-Land. We defined different observation scenarios to emulate the revisiting times of Landsat 8 (16 d) and the Thermal infraRed Imaging Satellite for High-resolution Natural resource Assessment (TRISHNA) (3 d) while accounting for cloud cover. We replicated the experiments 100 times at each experimental site to assess the robustness of the assimilation process with respect to cloud cover under both revisiting scenarios. We performed the assimilation using two different approaches: a sequential scheme (particle filter) and a smoother (particle batch smoother). The results show that LST DA using the smoother reduced the normalized root mean square error (nRMSE) of the SWE simulations from 61 % (open loop) to 17 % and 13 % for 16 d revisit and 3 d revisit respectively in the absence of clouds. We found similar but higher nRMSE values by removing observations due to cloud cover but with a substantial increase in the standard deviation of the nRMSE of the replicates, highlighting the importance of revisiting times in the stability of the assimilation performance. The smoother largely outperformed the particle filter algorithm, suggesting that the capability of a smoother to propagate the information along the season is key to exploit LST information for snow modelling. Finally, we have compared the benefit of assimilating LST with synthetic observations of fractional snow cover area (FSCA). LST DA performed better than FSCA DA in all the study sites, suggesting that the information provided by LST is not limited to the duration of the snow season. These results suggest that the LST data assimilation has an underappreciated potential to improve snowpack simulations and highlight the value of upcoming TIR missions to advance snow hydrology