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Article Dans Une Revue Journal of the European Ceramic Society Année : 2016

Consolidation and conversion of carbon powders into TiC by reactive chemical vapour infiltration

Résumé

Ceramic samples were prepared using a hybrid process in which the ceramic powder route was combined with Reactive Chemical Vapour Infiltration, a new gas phase route. In this technique, a carbide growth occurs from the conversion of a carbon-bearing powder and slows down with increase in carbide thickness due to solid-state diffusion limitation. This self-limitation is expected to allow a self-regulation of the growth between the interior and the surface of the sample and thus a better homogeneity. The chosen carbide was TiC obtained by reacting H2 and TiCl4 with a carbon powder introduced by slurry impregnation in felts. At 950°C, the carbide infiltration is homogeneous with depth but the powder is not consolidated, while at 1050°C the better conversion rate of carbon into carbide allows the consolidation but the infiltration is limited to only about 250 µm. The consolidation depth can be improved with time-temperature steps between both temperatures.

Domaines

Matériaux
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Dates et versions

hal-01617819 , version 1 (17-10-2017)

Identifiants

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Olivier Ledain, Sylvain Jacques, Laurence Maillé. Consolidation and conversion of carbon powders into TiC by reactive chemical vapour infiltration. Journal of the European Ceramic Society, 2016, 36 (3), pp.481-488. ⟨10.1016/j.jeurceramsoc.2015.11.008⟩. ⟨hal-01617819⟩
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